Anomalous orbital admixture in ammine complexes
نویسندگان
چکیده
منابع مشابه
Organometallic cis-Dichlorido Ruthenium(II) Ammine Complexes
Bifunctional neutral half-sandwich RuII complexes of the type [(η6-arene)Ru(NH3)Cl2] where arene is p-cym (1) or bip (2) were synthesised by the reaction of N,N-dimethylbenzylamine (dmba), NH4PF6 and the corresponding RuII arene dimer, and were fully characterised. X-ray crystallographic studies of [(η6-p-cym)Ru(NH3)Cl2]·{(dmba-H)(PF6)} (1a) and [(η6-bip)Ru(NH3)Cl2] (2) show extensive H-bond in...
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2015
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2015.05.032